en Iodate sulfate

Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements.^[1] Related compounds include the iodate selenates^[2] and chromate iodates.^[3]

Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.^[4]

List

formula	name	formula weight	system	space group	cell Å	volume	density	comments	ref
Na₇(IO₃)(SO₄)₃		624.01	orthorhombic	P2₁2₁2₁	a=6.839 b=10.851 c=18.519 Z=4	1374.2	3.016	at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm	^[5]
Na₉(IO₃)(SO₄)₄	Hectorfloresite		monoclinic	P2₁/a	a = 18.775 b = 6.9356 c = 14.239 β = 108.91° Z = 4				^[5]^[6]
K₂SO₄·HIO₃		350.17	monoclinic	P2₁/n	a=7.4215 b=7.1578 c=13.802 β=93.330° Z=4	731.9	3.178	colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm	^[7]
K₃Na₅Mg₅(IO₃)₆(SO₄)₆(H₂O)₅			trigonal	P3c1
K_7.2Na_8.8Mg₁₀(IO₃)₁₂(SO₄)₁₂(H₂O)₁₂	Fuenzalidaite		trigonal	P3c1	a = 9.4643 c = 27.336	2,120.52		colourless; Uniaxial (-) n_ω = 1.622 n_ε = 1.615; Birefringence = 0.007	^[5]^[8]^[9]
Nb₂O₃(IO₃)₂(SO₄)		679.68	monoclinic	P2₁	a=5.299 b=20.479 c=5.452 β=119.095° Z=2	517.0	4.366	band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C	^[5]^[10]
Ce(IO₃)₂(SO₄)	CISO	585.98	orthorhombic	P2₁2₁2₁	a=7.5366 b=8.9787 c=11.6121 Z=4	785.78	4.953	yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm	^[11]
Sm(IO₃)(SO₄)			monoclinic	P2₁/c	a=9.3148 b=6.8678 c=8.2852 β=104.701°				^[12]
Sm₂(IO₃)₃(SO₄)OH·3H₂O			triclinic	P1	a 7.3858 b 9.6166 c 11.8629 α=66.482° β=76.884° γ=69.101°				^[12]
Eu(IO₃)(SO₄)			monoclinic	P2₁/c	a=9.3083 b=6.8460 c=8.2575 β=104.696°				^[5]^[1]
Eu₂(IO₃)₃(SO₄)OH·3H₂O			triclinic	P1	a=7.3666 b=9.5817 c=11.8263 α=66.5365° β=76.8591° γ=69.1131°				^[12]
Dy(IO₃)(SO₄)(H₂O)			orthorhombic	P2₁2₁2₁	a=7.3088 b=9.4824 c=11.7302 α=66.6573° β=76.8745° γ=69.2970°				^[5]
Dy(IO₃)(SO₄)(H₂O)₃			orthorhombic	P2₁2₁2₁	a=6.682 b=8.791 c=13.632				^[1]
Dy₂(IO₃)₃(SO₄)OH·3H₂O			triclinic	P1					^[12]
Hg₂(IO₃)₂(SO₄)			monoclinic	C2/c	a=12.040 b=4.7133 c=15.533 β=102.43°				^[13]
Hg₂(IO₃)₂(SO₄)(H₂O)			monoclinic	C2	a=11.767 b=4.9190 c=7.8076 β=97.10°			band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C	^[13]
Bi(IO₃)(SO₄)		479.94	monoclinic	P2₁/c	a=9.4355 b=6.9168 c=8.3374 β=105.168° Z=4	525.17	6.070	band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless	^[14]
Bi₂O(SO₄)(IO₃)₂			monoclinic	P2₁/n	a=7.2391 b=17.907 c=7.7964 β = 109.652° Z =4				^[4]
AgBi(SO₄)(IO₃)₂		1525.42	triclinic	P1	a=5.5189 b=6.9129 c=11.8527 α=90.598° β=92.151° γ=109.895° Z=1	424.78	5.963	colourless; SHG 3.0 × KDP	^[15]
CdBi(IO₃)(SO₄)₂		688.40	monoclinic	P2₁/c	a=12.777 b=6.8491 c=9.984 β=103.23° Z=4	850.5	5.376	band gap 4.03 eV; birefringence 0.100 at 1064 nm	^[14]

References

^ ^a ^b ^c Lu, Huangjie; Guo, Xiaojing; Wang, Yaxing; Diefenbach, Kariem; Chen, Lanhua; Wang, Jian-Qiang; Lin, Jian; Wang, Shuao (2019). "Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation". Dalton Transactions. 48 (34): 12808–12811. doi:10.1039/C9DT02387A. ISSN 1477-9226. PMID 31348473. S2CID 198911627.
^ Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023). "[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology". Inorganic Chemistry Frontiers. 10 (10): 3121–3130. doi:10.1039/D3QI00415E. ISSN 2052-1553. S2CID 258123310.
^ Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006). "Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2". Journal of Solid State Chemistry. 179 (4): 1192–1201. Bibcode:2006JSSCh.179.1192S. doi:10.1016/j.jssc.2006.01.017.
^ ^a ^b Shi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017). "Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters". Solid State Sciences. 63: 54–61. Bibcode:2017SSSci..63...54S. doi:10.1016/j.solidstatesciences.2016.11.010.
^ ^a ^b ^c ^d ^e ^f Ding, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units". Chemical Communications. 57 (75): 9598–9601. doi:10.1039/D1CC03483A. ISSN 1359-7345. PMID 34546233. S2CID 237584872.
^ George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989). "Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral". American Mineralogist. 74 (9–10): 1207–1214. Retrieved 2023-09-11.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^ Bai, Zhiyong; Ok, Kang Min (2023). "Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3". Inorganic Chemistry Frontiers. 10 (6): 1919–1925. doi:10.1039/D3QI00192J. ISSN 2052-1553. S2CID 257071174.
^ "Fuenzalidaite". Mindat.org.
^ Konnert, Judith A.; Evans, Howard T.; McGee, James J.; Ericksen, George E. (October 1994). "Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)". American Mineralogist. 79 (9–10): 1003–1008. Bibcode:1994AmMin..79.1003K. Retrieved 2023-09-11.
^ Tang, Hong-Xin; Zhang, Yu-Xiao; Zhuo, Chao; Fu, Rui-Biao; Lin, Hua; Ma, Zu-Ju; Wu, Xin-Tao (2019-03-18). "A Niobium Oxyiodate Sulfate with a Strong Second-Harmonic-Generation Response Built by Rational Multi-Component Design". Angewandte Chemie. 131 (12): 3864–3868. Bibcode:2019AngCh.131.3864T. doi:10.1002/ange.201813122. ISSN 0044-8249. S2CID 243005250.
^ Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-12-14). "From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence". Chemistry of Materials. 33 (23): 9317–9325. doi:10.1021/acs.chemmater.1c03053. ISSN 0897-4756. S2CID 244494818.
^ ^a ^b ^c ^d Aslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022). "Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)". Solid State Sciences. 129: 106918. Bibcode:2022SSSci.12906918A. doi:10.1016/j.solidstatesciences.2022.106918.
^ ^a ^b Li, Yi-Lin; Ji, Meng-Ya; Hu, Chun-Li; Chen, Jin; Li, Bing-Xuan; Lin, Yuan; Mao, Jiang-Gao (April 2022). "Explorations of New SHG Materials in Mercury Iodate Sulfate System**". Chemistry – A European Journal. 28 (19): e202200001. doi:10.1002/chem.202200001. ISSN 0947-6539. PMID 35156759. S2CID 246813632.
^ ^a ^b Li, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021). "Two bismuth iodate sulfates with enhanced optical anisotropy". Dalton Transactions. 50 (44): 16139–16146. doi:10.1039/D1DT02514G. ISSN 1477-9226. PMID 34677566. S2CID 239456548.
^ Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021). "AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement". Chemical Communications. 57 (30): 3712–3715. doi:10.1039/D0CC07862J. ISSN 1359-7345. PMID 33729224. S2CID 232262974.

[:3-1] Lu, Huangjie; Guo, Xiaojing; Wang, Yaxing; Diefenbach, Kariem; Chen, Lanhua; Wang, Jian-Qiang; Lin, Jian; Wang, Shuao (2019). "Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation". Dalton Transactions. 48 (34): 12808–12811. doi:10.1039/C9DT02387A. ISSN 1477-9226. PMID 31348473. S2CID 198911627.

[2] Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023). "[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology". Inorganic Chemistry Frontiers. 10 (10): 3121–3130. doi:10.1039/D3QI00415E. ISSN 2052-1553. S2CID 258123310.

[3] Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006). "Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2". Journal of Solid State Chemistry. 179 (4): 1192–1201. Bibcode:2006JSSCh.179.1192S. doi:10.1016/j.jssc.2006.01.017.

[:4-4] Shi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017). "Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters". Solid State Sciences. 63: 54–61. Bibcode:2017SSSci..63...54S. doi:10.1016/j.solidstatesciences.2016.11.010.

[:1-5] ^ ^a ^b ^c ^d ^e ^f Ding, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units". Chemical Communications. 57 (75): 9598–9601. doi:10.1039/D1CC03483A. ISSN 1359-7345. PMID 34546233. S2CID 237584872.

[6] George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989). "Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral". American Mineralogist. 74 (9–10): 1207–1214. Retrieved 2023-09-11.{{cite journal}}: CS1 maint: multiple names: authors list (link)

[7] Bai, Zhiyong; Ok, Kang Min (2023). "Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3". Inorganic Chemistry Frontiers. 10 (6): 1919–1925. doi:10.1039/D3QI00192J. ISSN 2052-1553. S2CID 257071174.

[8] "Fuenzalidaite". Mindat.org.

[9] Konnert, Judith A.; Evans, Howard T.; McGee, James J.; Ericksen, George E. (October 1994). "Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)". American Mineralogist. 79 (9–10): 1003–1008. Bibcode:1994AmMin..79.1003K. Retrieved 2023-09-11.

[10] Tang, Hong-Xin; Zhang, Yu-Xiao; Zhuo, Chao; Fu, Rui-Biao; Lin, Hua; Ma, Zu-Ju; Wu, Xin-Tao (2019-03-18). "A Niobium Oxyiodate Sulfate with a Strong Second-Harmonic-Generation Response Built by Rational Multi-Component Design". Angewandte Chemie. 131 (12): 3864–3868. Bibcode:2019AngCh.131.3864T. doi:10.1002/ange.201813122. ISSN 0044-8249. S2CID 243005250.

[11] Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-12-14). "From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence". Chemistry of Materials. 33 (23): 9317–9325. doi:10.1021/acs.chemmater.1c03053. ISSN 0897-4756. S2CID 244494818.

[:2-12] Aslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022). "Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)". Solid State Sciences. 129: 106918. Bibcode:2022SSSci.12906918A. doi:10.1016/j.solidstatesciences.2022.106918.

[:0-13] Li, Yi-Lin; Ji, Meng-Ya; Hu, Chun-Li; Chen, Jin; Li, Bing-Xuan; Lin, Yuan; Mao, Jiang-Gao (April 2022). "Explorations of New SHG Materials in Mercury Iodate Sulfate System**". Chemistry – A European Journal. 28 (19): e202200001. doi:10.1002/chem.202200001. ISSN 0947-6539. PMID 35156759. S2CID 246813632.

[:5-14] Li, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021). "Two bismuth iodate sulfates with enhanced optical anisotropy". Dalton Transactions. 50 (44): 16139–16146. doi:10.1039/D1DT02514G. ISSN 1477-9226. PMID 34677566. S2CID 239456548.

[15] Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021). "AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement". Chemical Communications. 57 (30): 3712–3715. doi:10.1039/D0CC07862J. ISSN 1359-7345. PMID 33729224. S2CID 232262974.

[1]

[2]

[3]

[4]

[5]

[6]

[7]

[8]

[9]

[10]

[11]

[12]

[13]

[14]

[15]

Agama	Bahasa	Biografi	Budaya	Ekonomi	Elektronika
Film	Filsafat	Geografi	Indonesia	Ilmu	Lingkungan
Masyarakat	Matematika	Militer	Mitologi	Musik	Olahraga
Pendidikan	Politik	Sastra	Sejarah	Seni	Teknologi

Iodate sulfate

List

References

Portal di Ensiklopedia Dunia