Sulfate fluoride
Class of chemical compounds
The sulfate fluorides are double salts that contain both sulfate and fluoride anions . They are in the class of mixed anion compounds . Some of these minerals are deposited in fumaroles .
Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1] [2]
Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.
List
Minerals
name
formula
ratio
system
space group
unit cell Å
volume
density
optical
references
Chukhrovite-(Ca)
Ca4.5 Al2 (SO4 )F13 ·12H2 O
1:13
Isometric
Fd 3
a = 16.749 Z=8
4698.6
2.23
isotropic n = 1.432
[3]
Chukhrovite-(Ce)
Ca3 (Y,Ce)(AlF6 )2 (SO4 )F · 10H2 O
1:13
Isometric
Fd 3
[4]
Chukhrovite-(Y)
Ca3 (Ce,Y)(AlF6 )2 (SO4 )F · 10H2 O
1:13
Isometric
Fd 3
[5]
Chukhrovite-(Nd)
Ca3 (Nd,Y)Al2 (SO4 )F13 ·12H2 O
1:13
Isometric
Fd 3
a = 16.759 Z=8
4,707.0
2.42
isotropic n α = 1.443
[6]
Meniaylovite
Ca4 [(SO4 )(SiF6 )(AlF6 )]F · 12H2 O
1:13
Isometric
Fd 3
a = 16.722 Z=8
4,675.89
Isotropic n = 1.43
Pseudograndreefite
Pb6 (SO4 )F10
1:10
Orthorhombic
F 2 2 2
a = 8.51 b = 19.57 c = 8.49 Z=4
1,413.93
Biaxial (+) n α = 1.864 n β = 1.865 n γ = 1.873
2V: measured: 30° , calculated: 40°
Max birefringence: δ = 0.009
[7]
Creedite
Ca3 SO4 Al2 F8 (OH)2 · 2H2 O
1:8
Monoclinic
B 2/b
a = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=4
1,194.02
2.713
Biaxial (-) n α = 1.461 n β = 1.478 n γ = 1.485
Max birefringence: δ = 0.024
[8]
Thermessaite
K2 AlF3 (SO4 )
1:3
Orthorhombic
Pbcn
a = 10.81 b = 8.336 c = 6.822
614.75
2.77
Grandreefite
Pb2 (SO4 )F2
1:2
monoclinic
A2/a
a = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4
523.15
7.15
Biaxial (+) n α = 1.872 n β = 1.873 n γ = 1.897
2V: Measured: 23°
Max Birefringence: δ = 0.025
[9]
Arangasite
Al2 F(PO4 )(SO4 ) · 9H2 O
1:1
monoclinic
P2/a
a = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2
725.7
2.01
Biaxial (+) ?n α = 1.493(5) n γ = 1.485(5)
Max birefringence: δ = 0.008
[10] [11]
Khademite
Al(SO4 )F · 5H2 O
1:1
orthorhombic
a = 11.17 b = 13.05 c = 10.88
1,585.96
1.925
Biaxial (-) n α = 1.440 n β = 1.460 n γ = 1.487
2V: measured: 68° calculated: 84°
Max birefringence δ = 0.047
colourless
[12]
Kogarkoite
Na3 (SO4 )F
1:1
Monoclinic
?P 21
a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=12
1,366.58
2.676
Biaxial (+) n α = 1.439 n β = 1.439 n γ = 1.442
Max Birefringence: δ = 0.003
[13]
kononovite
NaMg(SO4 )F
1:1
monoclinic
C 2/c
a = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4
367.4
2.91
biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2V meas = 75°
Max birefringence: δ = 0.008
[14]
Lannonite
Mg2 Ca4 Al4 (SO4 )8 F8 · 24H2 O
8:8
Tetragonal
I 4/m
a = 6.860 c = 28.053
1,320.16
2.22
Uniaxial (+) n ω = 1.460 n ε = 1.478
Max Birefringence:δ = 0.018
[15]
Sulphohalite
Na6 (SO4 )2 FCl
2:1
Isometric
Fm3 m
Isotropic
[16]
Uklonskovite
NaMgSO4 F•2H2 O
1:1
monoclinic
a = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23°
273.34
Biaxial (+) n α = 1.476 n γ = 1.500
Max Birefringence δ = 0.024
[17]
Vlodavetsite
AlCa2 (SO4 )2 F2 Cl · 4H2 O
2:2
Tetragonal
I 4/m
a = 6.870, c = 13.342 Z=2
629.70
Uniaxial (+) n ω = 1.509 n ε = 1.526
Max birefringence: δ = 0.017
[18]
Schairerite
Na21 (SO4 )7 ClF6
7:6
trigonal
3_ 2/m
a = 12.17 c = 19.29
2,474.25
2.67
Uniaxial (+) n ω = 1.440 n ε = 1.445
Max birefringence: δ = 0.005
[19]
Galeite
Na15 (SO4 )5 F4 Cl
5:4
Trigonal
a = 12.17 c = 13.94
1,788.03
Uniaxial (+) n ω = 1.447 n ε = 1.449
Max Birefringence: δ = 0.002
[20]
Fluorellestadite
Ca10 (SiO4 )3 (SO4 )3 F2
3:2
hexagonal
a = 9.53 c = 6.91
543.49
3.03
Uniaxial (-) n ω = 1.655 n ε = 1.650
Max birefringence:δ = 0.005
[21]
Straßmannite
Al(UO2 )(SO4 )2 F·16H2 O
2:1
monoclinic
C 2/c
a = 11.0187 b = 8.3284 c = 26.673 β = 97.426°
2427.2
2.20
pale yellowish green
Biaxial (-) n α = 1.477(2) n β = 1.485(2) n γ = 1.489(2)
2V: measured: 70° calculated: 70.2°
Max birefringence: δ = 0.012
[22]
Svyazhinite
(Mg,Mn2+ ,Ca)(Al,Fe3+ )(SO4 )2 F · 14H2 O
2:1
triclinic
a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08°
510.29
Biaxial (-) n α = 1.423 n β = 1.439 n γ = 1.444
2V: calculated: 56°
Max birefringence: δ = 0.021
[23]
Wilcoxite
MgAl(SO4 )2 F · 17H2 O
2:1
triclinic
P 1
a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487
579.6
1.58
Biaxial (-) n α = 1.424 n β = 1.436 n γ = 1.438
2V: measured: 48° , calculated: 44°
Max birefringence: δ = 0.014
[24]
Krasheninnikovite
KNa2 CaMg(SO4 )3 F
3:1
hexagonal
P63 /mcm
a = 16.6682 c = 6.9007 Z = 6
1660.36
2.68
Uniaxial (-) n ω = 1.500 n ε = 1.492
Max birefringence: δ = 0.008
[25]
Shuvalovite
K2 (Ca2 Na)(SO4 )3 F
3:1
orthorhombic
Pnma
a = 13.2383 b = 10.3023 c = 8.9909 Z = 4
1226.22
2.64
biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20
[26]
Thermessaite-(NH4)
(NH4 )2 AlSO4 F3
1:3
orthorhombic
Pbcn
a = 11.3005 b = 8.6125 c = 6.8501 Z = 4
666.69
[27]
Artificial
name
formula
MW
ratio
system
space group
unit cell
volume
density
optical
CAS
references
LiMgFSO4
1:1
triclinic
P 1
a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β =107.40 and γ =97.50° Z=2
[28]
NaMgSO4 F
1:1
monoclinic
C 2/c
Z=4
109.802
2.84
[29]
Na2 AlSO4 F3
1:1
monoclinic
P 2/c
a =6.3562 b =6.2899 c =7.1146 β =115.687° Z=2
256.33
2.928
[30]
Li4 NH4 Al(SO4 )2 F4
2:4
monoclinic
C 2/c
a =13.6561 b =4.9761 c =13.9919 β =92.135° Z=4
950.2
2.383
[30]
Na4 TiF4 (SO4 )2
2:4
[31]
β-K3 [SO4 ]F
1:1
tetragonal
I 4/mcm
a = 7.2961 c = 10.854
[32]
α-K3 [SO4 ]F
1:1
cubic
Pm3 m
a ≈5.43 ≥585 °C
[32]
KMgSO4 F
178.47
1:1
orthorhombic
Pna 21
a =12.973 b =6.4585 c =10.635 Z=8
891.1
2.661
colourless
[33] [34]
Li6 K3 Al(SO4 )4 F4
4:4
triclinic
P 1
a =5.0304 b =9.5690 c =9.7078 α =70.968° β =75.531° γ =75.183° Z=1
420.08
2.554
[30]
sodium calcium sulfapatite
Na6 Ca4 (SO4 )6 F2
6:2
K3 Ca2 (SO4 )3 F
3:1
orthorhombic
Pn21 a
a=13.467 b=10.521 c=9.167 Z=4
1299.9
[35]
[N2 C10 H12 ] TiF4 SO4
378.16?
1:4
triclinic
P 1
a=8.691 b=9.208 c=9.288 α =68.56 β=84.30 γ= 81.59 Z=2
683.6
1.837
colourless
[31]
[N2 C10 H12 ]TiF2 (SO4 )2
436.22?
2:2
triclinic
P 1
a=4.5768 b=8.9162 c=10.1236 α =112.888 β=95.196 γ =98.706 Z=1
371.11
1.952
colourless
[31]
Rb2 TiF2 (SO4 )2 · 2H2 O
1:1
[36]
Cs2 TiF2 (SO4 )2 · 3H2 O
1:1
[36]
[N2 C6 H16 ]V(SO4 )2 F
378.27
2:1
monoclinic
P 21 /c
a=10.262 b =17.761 c=7.0518 β=93.93 Z=4
1282.3
1.959
green
[31]
Na2 VF3 SO4
1:3
[31]
Na3 CrF2 (SO4 )2
2:2
[31]
LiMnSO4 F
1:1
monoclinic
a=13.2406 b=6.4082 c=10.0229 β=120.499
732.76
[37]
[N2 C6 H16 ]2+ Mn2 F2 (SO4 )2
2:2
[31]
Li2 MnF3 (SO4 )
1:3
pink-brown
[38]
(NH4 )2 MnF3 (SO4 )
1:3
pink-brown
[38]
Na2 MnF3 (SO4 )
1:3
pink-brown
[38]
Dipotassium trifluorosulfato manganate(III)
K2 MnF3 (SO4 )
1:3
pink-brown
[38]
FeFSO4
170.91
1:1
monoclinic
C 2/c
a = 7.3037 b = 7.0753 c = 7.3117 β = 119.758°
328.017
3.461
[39]
K2 FeF3 SO4
1:3
[31]
Li3 FeF2 (SO4 )2 ·H2 O
2:2
[31]
[N2 C6 H16 ]Fe(SO4 )2 F
383.18
2:1
monoclinic
P 21 /c
a=10.2220 b=17.6599 c=7.0437 β=93.894 Z=4
1268.59
2.006
brown
[31]
LiFeFSO4
177.85
1:1
triclinic
P 1
a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865°
182.44
3.237
grass green
[39]
sodium ferrous sulfate fluoride
NaFeFSO4
193.91
1:1
monoclinic
P 21 /c
a = 6.6739 b = 8.6989 c = 7.1869 β = 113.525°
382.567
3.366
[39]
sodium ferrous sulfate fluoride dihydrate
NaFeFSO4 ·2H2 O
1:1
monoclinic
P 21 /m
a=5.75959 b=7.38273 c=7.25047 β=113.3225
283.109
white
[40]
trisodium ferric disulfate difluoride
Na3 Fe(SO4 )2 F2
2:2
orthorhombic
Pnca
a = 6.6419 b = 8.8115 c = 14.0023
[41]
NaCoFSO4
1:1
monoclinic
C 2/c
a=6.6687 b=8.6251 c=7.1444 β=114.323
374.46
[42]
NaCoFSO4 ·2H2 O
1:1
monoclinic
P 21 /m
a=5.73364 b=7.31498 c=7.18640 β=113.5028
276.40
pink
[40]
NH4 CoFSO4 ·2H2 O
1:1
[43]
KCoFSO4 ·2H2 O
1:1
[43]
NaNiFSO4 ·2H2 O
1:1
monoclinic
P 21 /m
a=5.70118 b=7.27603 c=7.15634 β=113.8883
271.429
green
[40]
LiZnSO4 F
1:1
orthorhombic
Pnma
7.40357 b=6.32995 c=7.42016
347.740
[44]
KZnSO4 F
219.53
1:1
orthorhombic
Pna 21
a =13.0602 b =6.4913 c =10.7106 Z=8
908.02
3.212
transparent <190 nm
[34]
K2 Zn3 (SO4 )(HSO4 )2 F4
1:4
orthorhombic
Cmc 21
a=17.725 b=7.6650 c=9.7505 Z=4
1324.7
3.212
colourless
[45]
Li4 RbAl(SO4 )2 F4
2:4
monoclinic
C 2/c
a=13.6503 b=4.984 c=14.0081 β=91.509° Z=4
948.82
2.858
[46]
Y(SO4 )F
203.97
1:1
orthorhombic
Pnma
a =8.3128, b =6.9255, c =6.3905 Z=4
367.90
3.682
[47]
YSO4 F·H2 O
1:1
monoclinic
P 21 /n
a =4.9707 b =7.306 c =11.493 β =96.95°
birefringence 0.0357 at 546 nm
[48]
Y2 Cu(OH)3 (SO4 )2 F·H2 O
521.52
2:1
monoclinic
P 21 /n
a =11.6889, b =6.8660, c =12.5280, β =97.092° Z=4
997.8
3.472
blue
[47]
KYSO4 F2
1:2
monoclinic
P 21 /m
a =6.4402 b =5.7784 c =6.992 β =113.684° Z=2
238.30
3.652
band gap 7.79 eV; birefringence 0.015 @ 546.1 nm
[49]
RbYSO4 F2
1:2
monoclinic
P 21 /m
a =6.5347 b =5.8212 c =7.1383 β =114.332° Z=2
247.42
4.140
band gap 7.82 eV; birefringence 0.02 @ 546.1 nm
[49]
Zr2 O2 F2 SO4 · 6H2 O
1:2
[50]
α-K3 ZrF5 SO4 · H2 O
1:5
[36]
K2 ZrF4 SO4
1:4
[36]
K2 ZrF2 (SO4 )2 · 2.5H2 O
2:2
[36]
K3 Zr2 F9 SO4 · 2H2 O
1:9
[36]
(NH4 )3 Zr2 F9 SO4 · 2H2 O
1:9
[36]
(NH4 )2 ZrF4 SO4
1:4
[36]
(NH4 )2 ZrF2 (SO4 )2 · 2.5H2 O
2:2
[36]
Rb2 ZrF4 SO4
1:4
[36]
Rb2 ZrF2 (SO4)2 · 3H2 O
2:2
[36]
Rb3 Zr2 F9 SO4 ·2H2 O
1:9
[36]
RbZr2 O2 F(SO4 )2 · 5H2 O
2:1
[36]
Cs2 ZrF4 SO4
1:4
[36]
Cs2 ZrF2 (SO4 )2 · 2H2 O
2:2
[36]
Cs8 Zr4 F2 (SO4 )11 · 16H2 O
11:2
[36]
CsZr2 O2 F(SO4 )2 · 6H2 O
2:1
[36]
Zr2 O2 F2 SO4 · 5H2 O
1:2
[36]
triindium trifluoride sulfate ditellurite hydrate
In3 (SO4 )(TeO3 )2 F3 (H2 O)
866.74
1:3
orthorhombic
P 21 21 21
a=8.3115 b=9.4341 c=14.8068
1161.0
4.959
band gap 4.10 eV; white
[51]
4,4'-bipyridine distannous difluoride disulfate
(C10 H10 N2 )0.5 [SnF(SO4 )]
2:2
triclinic
P 1
a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2
398.3
2.608
colourless
[52]
diantimony dipotassium hexafluoride sulfate
K2 SO4 ·(SbF3 )2
531.76
1:6
monoclinic
P 21 /c
a=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4
973.40
3.629
colourless
[53]
diantimony dirubidium hexafluoride sulfate
Rb2 SO4 ·(SbF3 )2
624.50
1:6
monoclinic
P 21
a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2
516.1
4.018
colourless
[53]
tetraantimony hexarubidium dodecafluoride trisulfate
Rb6 Sb4 F12 (SO4 )3
1515.989
3:12
trigonal
P 3
a=16.9490 c=7.5405 Z=2
1875.94
4.026
white
53168-89-1
[54] [55]
hexaammonium dodecafluorotrisulfatotetraantimonate(III)
[NH4 ]6 Sb4 F12 (SO4 )3
3:12
trigonal
P 3
a=17.07 c=7.515 Z=3
1896
2.92
[56]
hexarubidium dodecafluorotrisulfatotetraantimonate(III)
Rb6 Sb4 F12 (SO4 )3
3:12
[56]
Li4 CsAl(SO4 )2 F4
2:4
monoclinic
C 2/c
a=13.574 b=5.0427 c=14.258 β=91.961° Z=4
975.7
3.103
[46]
tetraantimony hexacaesium dodecafluoride trisulfate
Cs6 Sb4 F12 (SO4 )3
1800.601
3:12
triclinic
P 1
a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=4
1394.3
4.289
white
53200-54-7
[54] [57]
antimony caesium difluoride sulfate
CsSbF2 SO4
388.72
1:2
orthorhombic
Pna 21
a=9.9759 b=11.6616 c=5.2968
515.20
4.19
clear, non-linear SH
[58]
LiLa2 F3 (SO4 )2
2:3
monoclinic
I2/a
a = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4
[59]
CeF2 (SO4 )
1:2
orthorhombic
Pca 21
a =8.3668 b =6.3600 c =8.3862
birefringence 0.361@ 546 nm; SHG 8×KDP
[60]
NdFSO4 ·H2 O
277.32
1:1
monoclinic
P 21 /n
a = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4
425.37
4.330
pink
[61]
NaPr2 F3 (SO4 )2
2:3
monoclinic
I2/a
a = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4
light green
[62]
LiEr2 F3 (SO4 )2
2:3
orthorhombic
Pbcn
a = 14.791, b = 6.336, c = 8.137
[59]
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride
[C4 H16 N3 ]6 [Sm4 F2 (SO4 )14 ]
2621.43
14:2
triclinic
P 1
a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=1
1903.9
2.286
colourless
[61]
TbFSO4 ·H2 O
292.00
1:1
monoclinic
P 21 /n
a = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4
426.9
4.543
colourless
[61]
gadolinium fluoride sulfate
GdF[SO4 ]
1:1
orthorhombic
Pnma
a=8.436 b=7.0176 c=6.4338 Z=4
[63]
γ-K2 HfF2 (SO4 )2 · 2H2 O
2:2
[36]
K2 HfF2 (SO4 )2 · 2.5H2 O
2:2
[36]
Na6 Pb4 (SO4 )6 F2
6:2
[64]
ThSO4 F2 .H2 O
1:2
monoclinic
P21 n
a = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4
502.98
colourless
[65]
potassium catena -di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrate
K2 UF2 O2 (SO4 )·H2 O
1:2
monoclinic
P 21 /c
a = 9.263 b = 8.672 c = 11.019 β = 101.60° Z = 4
867.1
3.83
greenish yellow
[66] [67]
(NH4 )2 [UO2 F2 (SO4 )]
triclinic
P 1
a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2
greenish yellow
[67]
(NH4 )6 [(UO2 )2 F4 (SO4 )3 ]
triclinic
P 1
a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1
greenish yellow
[67]
Cs2 [(UO2 )2 F4 (SO4 )]
greenish yellow
[67]
(NH4 )[UO2 F(SO4 )]
triclinic
P 1
a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=1
1.92
greenish yellow
[67]
RbUO2 SO4 F
orthorhombic
Pca 21
a=25.353 b=6.735 c=11.496 Z=12
[68] [69]
[N2 C6 H16 ][UO2 F2 (SO4 )]
520.29
1:2
triclinic
P 1
a=6.9105 b=9.6605 =10.1033 α =72.6594(14) β =87.068 γ =77.9568 Z=2
629.62
2.744
yellow
[70]
[N2 C6 H16 ][UO2 F(SO4 )]2
884.37
2:2
orthorhombic
Pmmn
a=6.9503 b=17.2147 c=7.0867 Z=2
847.90
3.464
yellow
[70]
[N2 C3 H12 ][UO2 F(SO4 )]2 ·H2 O
862.32
2:2
orthorhombic
Pnma
a=13.5775 b=14.6180 c=8.1168 Z=4
1610.99
3.555
yellow
[70]
[N2 C5 H14 ][UO2 F(H2 O)(SO4 )]2
907.38
2:2
monoclinic
P 1 21 /n1
a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=4
1935.0
3.115
yellow
[70]
[N2 C6 H18 ]2 [UO2 F(SO4 )]4 ·H2 O
1792.80
4:4
triclinic
P 1
a=10.8832 b=10.9386 c=16.5325 α =75.6604 β= 73.6101 γ =89.7726 Z=2
1824.73
3.263
yellow
[70]
[N2 C3 H12 ][UO2 F(SO4 )]2 ·H2 O
864.34
2:2
monoclinic
P 1 21 /n1
a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2
791.54
3.626
yellow
[70]
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfate
U4+ 3 F4 (SO4 )6 ·2NH4 ·H3 N-NH3
1436.6
6:4
monoclinic
C 2/c
a=15.2309 b=8.77998 c=18.8590 β =105.5030 Z=4
2432.69
4.392
green
[71]
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Salts and covalent derivatives of the
fluoride ion
Compounds containing the
sulfate group (
SO2− 4 )