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structure called bioctahedral. Many metal pentahalide and pentaalkoxide compounds exist in solution and the solid with bioctahedral structures. One example...

[TiCl4] colourless (t2g)0 tetrahedral [Ti2Cl10]2− colourless (t2g)3 bioctahedral [TiCl6]2− yellow (t2g)0 octahedral [CrCl6]3− ?? (t2g)3 octahedal [MnCl4]2−...

"Valence-Dependent Metal−Metal Bonding and Optical Spectra in Confacial Bioctahedral [Re2Cl9]z- (z= 1, 2, 3). Crystallographic and Computational Characterization...

formula VCl5. It is a black diamagnetic solid. The molecules adopt a bioctahedral structure similar to that of niobium(V) chloride. Chlorine cannot oxidise...

inorganic compound with the empirical formula WBr5. The compound consists of bioctahedral structure, with two bridging bromide ligands, so its molecular formula...

ligands and a η6-benzene. The complex can be viewed as an edge-shared bioctahedral structure. (Benzene)ruthenium dichloride dimer reacts with Lewis bases...

β-TcCl3. The α polymorph is also denoted as Tc3Cl9. It adopts a confacial bioctahedral structure. It is prepared by treating the chloro-acetate Tc2(O2CCH3)4Cl2...

orange solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two NbBr5 units are joined by a pair of bromide...

polymeric. It is one-dimensional polymer consisting of chains of edge-shared bioctahedral Hf2I8 subunits, similar to the motif adopted by HfCl4. The nonbridging...

for [Ru2(OAc)4(H2O)2]+. The complexes Nb2X6(SR2)3 adopt a face-sharing bioctahedral structures (X = Cl, Br; SR2 = thioether). As dimers of Nb(III), they...

yellow solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two TaBr5 units are joined by a pair of bromide...

analysis established that the methoxide and isopropoxides of niobium adopt bioctahedral structures. From a geometric perspective, the ten ethoxide ligand oxygen...

X-ray crystallography shows that the complex adopts an edge-shared bioctahedral structure, very similar to the Zr analogue. Hafnium tetrachloride is...

β-TcCl3. The α polymorph is also denoted as Tc3Cl9. It adopts a confacial bioctahedral structure. It is prepared by treating the chloro-acetate Tc2(O2CCH3)4Cl2...

black solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two TaI5 units are joined by a pair of iodide...

Applications to the molybdenum–molybdenum quadruple bond and to edge-sharing bioctahedral complexes". J. Am. Chem. Soc. 114 (12): 4915–4917. Bibcode:1992JAChS...

yellow solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two NbI5 units are joined by a pair of iodide...

Re2Cl10. This red-brown solid is paramagnetic. Rhenium pentachloride has a bioctahedral structure and can be described as Cl4Re(μ-Cl)2ReCl4. The (μ-Cl)2 part...

ditechnetium(III) tetraacetate dichloride and hydrogen chloride at 300 °C. It has a bioctahedral structure, consisting of triangular Tc3Cl9 units with C3v symmetry, with...

analysis established that the methoxide and isopropoxides of niobium adopt bioctahedral structures. From a geometric perspective, the ten ethoxide ligand oxygen...

colourless d8, 18e− trigonal bipyramidal [Fe2(CNEt)9]0 yellow d8 confacial bioctahedral see Fe2(CO)9 [Fe(CNMe)6]2+ colourless d6, 18e− octahedral [Co2(CN-t-Bu)8]0...

β-TcCl3. The α polymorph is also denoted as Tc3Cl9. It adopts a confacial bioctahedral structure. It is prepared by treating the chloro-acetate Tc2(O2CCH3)4Cl2...

Anionic carbido clusters are also known, including [Ru5C(CO)14]2− and the bioctahedral cluster [Ru10C2(CO)24]2−. Ru3(CO)12 -derived carbido compounds have been...

polymeric. It is one-dimensional polymer consisting of chains of edge-shared bioctahedral Hf2I8 subunits, similar to the motif adopted by HfCl4. The nonbridging...

complexes Nb2Cl6(SMe2)3 is one such example. It adopts a face-sharing bioctahedral structure with a Nb(III)=Nb(III) bond, spanned by two chloride and one...