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Pertechnetyl fluoride

Pertechnetyl fluoride
Identifiers
3D model (JSmol)
  • InChI=1S/FH.3O.Tc/h1H;;;;/q;;;;+1/p-1
    Key: OYCMXSPACZPBDD-UHFFFAOYSA-M
  • O=[Tc](=O)(=O)F
Properties
TcO
3F
Molar mass 165,00 g/mol
Appearance yellow substance
Melting point 18.3 °C (64.9 °F; 291.4 K)
Boiling point 100 °C (212 °F; 373 K)
insoluble
Related compounds
Related compounds
 Lanthanum oxyfluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pertechnetyl fluoride is an inorganic compound, a salt of technetium and hydrofluoric acid with the chemical formula TcO
3F. The compound was originally synthesized by H. Selig and G. Malm in 1963.[1][2]

Synthesis

Physical properties

The compound forms a yellow substance.[4]

Chemical properties

The compound can be hydrolyzed to produce pertechnetic acid and hydrofluoric acid.

It also reacts with arsenic pentafluoride or antimony pentafluoride.[5]

References

  1. ^ Schmidbaur, Hubert; Schwarz, W. H. Eugen (21 April 2021). "Permanganyl Fluoride: A Brief History of the Molecule MnO 3 F and of Those Who Cared For It". Chemistry – A European Journal. 27 (23): 6848–6859. doi:10.1002/chem.202004759. ISSN 0947-6539. PMC 8247864. PMID 33219726.
  2. ^ Baran, Enrique J. (1 January 1975). "Vibrational Properties of Pertechnetyl Fluoride". Spectroscopy Letters. 8 (8): 599–603. doi:10.1080/00387017508067365. ISSN 0038-7010. Retrieved 22 March 2023.
  3. ^ Selig, H.; Malm, J. G. (1 April 1963). "The preparation and properties of pertechnetyl fluoride, TcO3F". Journal of Inorganic and Nuclear Chemistry. 25 (4): 349–351. doi:10.1016/0022-1902(63)80183-9. ISSN 0022-1902. Retrieved 22 March 2023.
  4. ^ Lawroski, Stephen (1963). "Research and development on nonaqueous processing". Reactor Fuel Processing. 7 (1). U.S. Argonne National Laboratory.: 28. Retrieved 22 March 2023.
  5. ^ Supeł, Joanna; Abram, Ulrich; Hagenbach, Adelheid; Seppelt, Konrad (1 July 2007). "Technetium Fluoride Trioxide, TcO 3 F, Preparation and Properties". Inorganic Chemistry. 46 (14): 5591–5595. doi:10.1021/ic070333y. ISSN 0020-1669. PMID 17547395. Retrieved 22 March 2023.
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