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Nitrate chlorides

Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid salts,[1] and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.

Formation

Nitrate chloride compounds may be formed by mixing solutions of chloride and nitrate slats, the addition of nitric acid to a chloride salt solution, or the addition of hydrochloric acid to a nitrate solution. Most commonly water is used as a solvent, but other solvents such as methylene dichloride, methanol or ethanol can be used.

Minerals

name formula ratio

NO3:Cl

mw system space group unit cell Å volume density optical references
Buttgenbachite Cu19(NO3)2(OH)32Cl4 · 2H2O 2:4 hexagonal P63/mmc a = 15.75 Å, c = 9.161 Å Z=1 1968 4.538 Blue

Uniaxial (+) nω = 1.738 nε = 1.752

birefringence: δ = 0.014

[2][3]
Lislkirchnerite Pb6Al(OH)8Cl2(NO3)5·2H2O 5:2 monoclinic P21/n a = 10.7834(6) Å, b = 9.0584(5) Å, c = 13.6178(9) Å

β = 102.28(2)°

1300 [4]
Sveite KAl7(NO3)4(OH)16Cl2 · 8H2O 4:2 Monoclinic a = 10.89 Å, b = 13.04 Å, c = 30.71 Å

β = 92.1°

4,358 white

Biaxial (+) nα = 1.501 nβ = 1.503 nγ = 1.535

2V: calculated = 30°

Max Birefringence = δ = 0.034

[5]
Pb8O3(OH)5(NO3)4Cl 4:1 Monoclinic a = 14.831(3) Å, b = 7.659(2) Å, c = 10.186(2) Å

β = 108.64(3)°

1096 colourless [6]

List

name formula ratio

NO3:Cl

mw system space group unit cell Å volume density comment references
Chlorine nitrate O2NOCl orthorhombic P212121 a = 3.856 b = 6.755 c = 12.07 Z=46 314.5 2.058 at −166 °C (related compound) [7]
anilinium chloride nitrate (C6H8N)2ClNO3 1:1 triclinic P1 a = 8.418 b = 9.648 c = 10.036 α = 62.993° β = 86.798° γ = 72.999° [8]
o-Phenylenediaminium chloride nitrate orthorhombic Pnma a = 7.3695 b = 8.2367 c = 14.2398 Z=4 864.36 1.596 [9]
l-lysinium(2+) chloride nitrate L-Lys2+·Cl−·NO3- 1:1 monoclinic P21 a 8.8022 b 7.0096 c 20.2169 β 95.226° [10]
L-Lysine L-lysinium dichloride nitrate 2C6H15N2O2+·H+·NO3-·2Cl- 1:2 428.32 orthorhombic P212121 a 4.9846 b 20.604 c 20.663 Z=4 2122.1 1.341 colourless [11]
L-cysteinium sodium nitrate chloride 1:1 monoclinic P21 a=18.5, b=5.22, c=7.22 β=103.83° 678 transparent from 328 to 1400nm; SHG 0.51 ×KDP [12]
Bis(L-ornithinium) chloride nitrate sulfate 2C5H14N2O22+·Cl-·NO3-·SO42- 461.88 monoclinic C2 a 13.872 b 9.578 c 9.178 β 125.35° Z=2 994.6 1.542 [13]
(μ4-octahydroxycucurbit(5)uril)-(μ2-nitrato)-aqua-di-potassium chloride nonahydrate {[K(H2O)](NO3⊂C30H28N20O20)[K(η2-NO3)]}Cl(H3O)22+·7H2O monoclinic P21/c a 13.8265 b 14.2642 c 25.143 β 92.711° Z=4 4953.2 1.806 colourless [14]
Thecotrichite Ca3(CH3COO)3Cl(NO3)2 • 6H2O 2:1 monoclinic P21/c a 23.5933 b 13.8459 c 6.8010 β 95.195° Z=4 2212.57 anthropogenic, formed on ceramics in damp wooden cupboards;

refractive index: nx = 1.491 nz = 1.494 stable to 110°C

[15]
di-μ-hydroxido-bis[triaqua(nitrato-κ2O,O′)scandium(III)] dichloride [Sc2(NO3)2(OH)2(H2O)6]Cl2 1:1 426.95 triclinic P1 a=6.7221 b=7.6279 c=8.5181 α=100.904° β=110.125° γ=102.329° Z=1 383.87 1.847 colourless @100K [16]
[Fe(Cl)4](Fe(NO3)2(OPPh2py)2 [17]
[Fe(NO3)2(Cl)(OPPh2py)]· CH2Cl2 monoclinic P21/n a 9.138 b 15.69 c 16.68 β 94.50° [17]
hexamethylphosphoric triamide Fe(NO3)2(Cl)(HMPA)1.5 [18]
hexamethylphosphoric triamide Fe(NO3)2(Cl)(HMPA)2 [18]
hexamethylphosphoric triamide Fe(NO3)(Cl)2(HMPA)2 monoclinic P21/c a 15.994 b 10.172 c 16.571 β 104.7° [18]
pypn=N,N′-bis(2-pyridylmethyl)-1,3-propanediamine

(N,N'-bis((pyridin-2-yl)methyl)propane-1,3-diamine)-dichloro-iron(iii) nitrate

[Fe(pypn)Cl2](NO3) monoclinic P21/c a 11.848 b 12.474 c 12.301 β 94.56° Cl in cis position [19]
pentaamminenitrocobalt(III) chloride nitrate [Co(NH3)5NO2](NO3)Cl orthorhombic Pnam a 14.814 b 9.623 c 7.309 @290K; photosalient (jumps under UV) [20][21][22]
trans-Dichloro-bis(ethylenediamine)-cobalt(III) nitrate [Co en2Cl2]NO3 monoclinic P21/n a = 6.348 b = 9.304 c = 9.853 β = 101.79° 569.6 1.82 green [23][24]
cis-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate [Co(en)2(NH3)Cl](NO3)2 [25]
trans-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate [Co(en)2(NH3)Cl](NO3)2 [25]
5-nitrosalicyliddineaminato tetraamino cobalt dichloride nitrate orange [26]
cis-Chlorobis(ethylenediamine)dodecylaminecobalt(III) nitrate cis-[Co(en)2(C12H25NH2)Cl](NO3)2 [27]
bis(1,4,7-triazacyclononane) nickel(ii) nitrate chloride monohydrate [Ni([9]aneN3)2](NO3)Cl·H2O orthorhombic Pna21 a 17.584 b 8.860 c 12.141 [28]
Bis[chlorobis(1,10-phenanthroline-N,N')(thiourea-S)nickel(II)] chloride nitrate diethanol solvate [NiCl(C12H8N2)2(CH4N2S)]2(NO3)Cl·­2C2H6O orthorhombic Fdd2 a 22.813 b 29.024 c 17.113 Z=8 11331 1.467 blue [29]
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-nickel(ii)) clathrate chloride trinitrate undecahydrate {[C14H17N2Ni(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl2(NO3)6·22H2O triclinic P1 a 16.671 b 16.678 c 20.442 α 112.772° β 101.844° γ 90.102° [30]
bis(bis(1,4,7-triazacyclonon-1-yl)pentane)-di-nickel(ii) trichloride nitrate pentadecahydrate [Ni2(EM5)2]Cl3NO3·15H2O orthorhombic Pbcn a 28.030 b 17.469 c 12.289 [31]
bis(bis(1,4,7-triazacyclonon-1-yl)hexane)-di-nickel(ii) dichloride dinitrate hexahydrate [Ni2(EM6)2]Cl3(NO3)2·6H2O triclinic P1 a 9.529 b 9.566 c 14.684 α 81.08° β 78.84° γ 88.82° [31]
dapsc = 2,6-diacetylpyridine-bis(semicarbazone)) [Ni(dapsc)(H2O)2]Cl(NO3)·H2O triclinic P1 a=6.9130 b=12.3410 α=114.8010 β=93.946 γ=103.7760 Z=2 933.10 1.735 green [32]
hexakis(1H-imidazole)-nickel(ii) chloride nitrate tetrahydrate [Ni(Im)6][(NO3)Cl(H2O)4] hexagonal P63m a 9.003 c 21.034 [33]
bis(M-2-chloro)-(nitrato-o)-(2,2 '-bipyridine-N.N ')-copper(II) Cu(2,2 '-BP)Cl NO3 triclinic P1 a = 7.515 b = 9.253 c = 10.283 α=112.181° β= 102.155° γ= 105.617° Z=2 597.4 1.769 green; dimer [34]
bis(M-2-chloro)-(nitrato-o)-(2,2 '-4,4'-dimethylbipyridine-N.N ')-copper(II) Cu(2, 2'-dmBP)ClNO3 dimer [34]
Chloro(1,10-phenanthroline-2-carboxamide oxime)copper(II) Nitrate [35]
bis(μ2-2,4,4,6,6-pentakis(2-pyridyloxy)cyclo-2,4,6-triphosphazene 2-oxide)-dichloro-nitrato-cobalt(ii)-di-copper chloride [{(N3P3(OC5H4N)5(O)CuCl)2Co(NO3)}Cl] orthorhombic Fddd a =22.639 b =28.202 c =45.260 [36]
Copper(II)–sparteine nitrate chloride CuII{(−)Sp}(NO3)Cl orthorhombic P212121 a 16.370 b 13.334 c 7.6803 [37]
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-copper(ii)) clathrate dichloride dinitrate hexadecahydrate {[C14H17N2Cu(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl4(NO3)4·32H2O triclinic P1 a 16.607 b 17.093 c 20.509 α 66.003° β 77.568° γ 89.155° [30]
copper(II)-di-2-pyridylamine complex chloride nitrate

(μ2-Chloro)-(nitrato-O)-(bis(2-pyridyl)amine-N,N')-copper(ii) hemihydrate

[Cu(dipyam)Cl(NO3)].0.5H2O monoclinic P21/a a 7.382 b 21.494 c 8.032 β 94.26 [38]
tipa=tri(4-imidazolylphenyl)amine

(μ3-tris(4-(Imidazol-1-yl)phenyl)amine)-chloro-zinc nitrate dimethylformamide solvate

[Zn(tipa)Cl]⋅NO3⋅2 DMF orthorhombic Pnna a=28.470 b=27.784 c=9.255 7321 1.044 [39]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 2:1 1029.39 hexagonal P63/mcm a = 9.5732 c = 15.820 Z=2 1255.6 2.723 UV cut off 231 nm; uniaxial; birefringence 0.14 @ 546 nm [40]
KRb2(NO3)2Cl 2:1 369.51 orthorhombic pbam a=12.1863 b=12.4072 c=5.8203 Z=4 880.02 2.789 transparent; birefringence = 0.084 at 1064 nm [41]
[Ru(NH3)5Cl](NO3)2 tetragonal I4 a = 7.5811 b = 7.5811 c = 10.535 605.5 1.896 yellow [42]
[RuNO(NH3)3(H2O)Cl](NO3)2 monoclinic Cc a = 13.7924 b = 6.9114 c = 12.3577 β = 111.863° Z = 4 1093.27 2.185 [43]
bis((μ2-chloro)-(nitrato)-(η5-pentamethylcyclopentadienyl)-rhodium(iii)) [Cp*Rh(η1-NO3)(μ-Cl)]2 monoclinic P21/n a 8.3874 b 10.4549 c 14.8585 β 104.385° [44]
chloro-(cyclohexylisocyano)-(η5-pentamethylcyclopentadienyl)-(triphenylphosphine)-rhodium nitrite nitrate dihydrate {[Cp*RhCl(PPh3)(CNC6H11)]2(NO2)(NO3)}·2H2O triclinic P1 a 10.319 b 10.5582 c 17.371 α 97.011° β 94.35° γ 112.154° [44]
[Rh(NH3)5Cl](NO3)2 tetragonal I4 a = 7.5858 b = 7.5858 c = 10.41357 Z=2 599.24 1.926 yellow [42]
bis(μ2-4'-(4-pyridyl)-2,2':6',2''-terpyridine)-bis(η5-pentamethylcyclopentadienyl)-tetra-chloro-di-rhodium-nickel dinitrate methanol solvate dihydrate {Cp*2Rh2[Ni(pyterpy)2]Cl4}(NO3)2 monoclinic C2/c a 53.4454 b 8.8419 c 33.7700 β 112.029° [45]
cis-dichlorobis(ethylenediamine)rhodium(III) nitrate [Rh(en)2Cl2]NO3 triclinic P1 a=8.619 b=6.528 c=11.687 α=I02.18 β=90.98 γ=112.46 Z=2 590.5 2.00 yellow [46]
trans-dichlorobis(ethylenediamine)rhodium(III) nitrate [Rh(en)2Cl2]NO3 monoclinic P21/n a = 6.441 b=9.281 c=10.010 β=102.42 Z=2 584.4 2.02 orange [46]
L=3,6,9,16,19,22-hexaazatricyclo[22.2.2.211,14]triacon-11,13,24,26(1),2 7,29-hexaene

(μ2-3,6,9,16,19,22-Hexa-azatricyclo(22.2.2.211,14)triaconta-1(26),11,13,24,27,29-hexaene)-dichloro-di-palladium(ii) dinitrate monohydrate

[Pd2LCl2](NO3)2·H2O monoclinic P2/c a 21.744 b 9.243 c 16.259 β 93.580° [47]
en=Ethylenediamine py=pyridine [Pd(en)(py)Cl]NO3 monoclinic P21/c a = 7.990, b = 16.058, c = 9.846 β = 103.81° Z = 4 [48]
4-Methylpyridine, [Pd(en)(4-Me-py)Cl]NO3 [48]
4-hydroxy-pyridine [Pd(en)(4-OH-py)Cl]NO3 [48]
4-NH2-py=4-aminopyridine [Pd(en)(4-NH2-py)Cl]NO3 [48]
tetrakis(μ-tris((diphenylphosphino)methyl)amine)-tetrachloro-pentadeca-silver tris(nitrate) octahydrate [Ag15(N-triphos)4(Cl4)](NO3)3 3649.32 orthorhombic C2221 a 18.702 b 36.975 c 28.652 Z=6 19813 1.835 [49]
bis(tetrakis(Triphenylphosphine)-silver) chloro-diphenyl-bis(nitrato-O,O')-tin diphenyl-tris(nitrato-O,O')-tin [Ag(PPh3)4][SnPh2(NO3)2(Cl,NO3)] triclinic P1 a 22.43 b 14.13 c 13.96 α 90.59° β 69.82° γ 64.58° [50]
barium chloride nitrate Ba(NO3)Cl orthorhombic Pnma a 8.9108 b 5.2991 c 8.3414 UV cutoff 213 nm; birefringence 0.009 @ 1064 nm [51]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [La(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.1798 c = 16.4174 Z=4 5426.0 1.150 [52]
tris(μ2-N',N''-((5-Chloro-2-oxy-1,3-phenylene)dimethylylidene)bis(benzohydrazide))-bis(ethanol)-di-lanthanum dinitrate chloride acetone solvate dihydrate [La2(H2L1)3(C2H5OH)2]·(Cl)·(NO3)2·((CH3)2CO)2·(H2O)2 monoclinic C2/c a 21.1020 b 18.5070 c 23.1880 β 114.452° [53]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [Ce(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.216 c = 16.483 Z=4 5469.6 1.147 [52]
Chloro-nitrato-pentakis(tetrahydrofuran)-cerium(iii) pentachloro-(tetrahydrofuran)-cerium(iv) [CeCl(NO3)(THF)5]+[CeCl5(THF)]− monoclinic P2/c a 12.138 b 11.299 c 14.066 β 104.31° [54]
Praseodymium dichloride nitrate pentahydrate [PrCl2(H2O)6][PrCl2(NO3)2(H2O)4] monoclinic P2/c a = 12.288 b = 6.484 c = 12.660 β = 91.91° Z = 4 green [55]
L=N,N′‐bis (salicylidene)‐1,2‐cyclohexanediamine [Pr(H2L)2(NO3)2Cl]·2CH2Cl2 941.14 tetragonal P43212 a=18.0936 c=16.3490 Z=4 5352.3 1.168 [56]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [Nd(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.1041 c = 16.4374 Z=4 5387.5 1.164 [52]
Chloro-bis(nitrato-O,O')-bis(tetramethyl (t-butyl(hydroxy)methylene)-bis(phosphonate)-O,O')-neodymium(iii) NdCl(NO3)2{[(MeO)2PO]2C(OH)tBu}2 monoclinic P21/a a 17.0961 b 9.3040 c 24.4989 β 110.244° [57]
tri-sodium hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-triacontakis(μ-2-thiophenecarboxylato)-tetrakis(2-thiophenecarboxylato)-decakis(μ-glycinato)-diglycine-docosa-aqua-octatetraconta-europium(iii) nitrate hexachloride 2-thiophenecarboxylic acid pentahydrate Na3[Eu48O6(OH)84(tca)34(gly)12(H2O)22]·2Htca·6Cl·6H2O·NO3 15118.80 triclinic P1 a 20.720 b 23.227 c 24.562 α 88.66° β 71.76° γ 63.57° Z=1 9960 2.500 [58]
sodium tetradecakis(μ-3-hydroxy-2-(hydroxymethyl)-2-methylpropanoato)-hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-octadecakis(μ-2-thiophenecarboxylato)-octakis(2-thiophenecarboxylato)-tetracosa-aqua-octatetraconta-terbium(iii) nitrate octakis(chloride) Na[Tb48O6(OH)84(fca)26(dmp)14(H2O)24]·4Hfca·NO3·8Cl 15154.02 monoclinic P21/n a 24.0145 b 32.9221 c 25.6605 β 97.521° Z=2 20112.9 2.490 [58]
L=2-methyl-8-hydroxyquinoline

tetrakis(μ-2-methylquinolin-8-olato)-(μ-chloro)-ethanol-dinitrato-di-nickel(ii)-dysprosium(iii) acetonitrile solvate

[Ni2IIDyIII(EtOH)(L2)4(NO3)2Cl] ⋅ CH3CN triclinic P1 a 11.1201 b 14.1566 c 15.448 α 78.625° β 73.918° γ 81.055° [59]
(tetrakis(μ-(1-phenylethyl)ammoniomethylphosphonato)-chloro-nitrato-di-erbium R- or S-[Er2(pempH)4(NO3)Cl] orthorhombic P21212 a 15.986 b 32.069 c 9.1593 quadruple stranded helix [60]
[{trans-PtCl(NH3)2}{μ-(H2N(CH2)6NH2)}{trans-PdCl(NH3)2](NO3)Cl yellow [61]
[{trans-PtCl(NH3)2}2{trans-Pt(thiazole)2}{H2N(CH2)6NH2}2]Cl3(NO3) [62]
[PtPy2(NH=CH-OH)Cl3]NO3 orthorhombic P212121 a = 10.381 b = 11.776 c = 13.848 Z = 4 1692.9 [63]
alpha pyridone cis-[Pt(NH3)2(C5H4NOH)Cl](NO3) triclinic P1 a=10.706 b=12.552 c=4.151 α =95.57° β=92.32° γ=99.05° Z=2 547.4 2.558 white needles [64]
[PtIV(trans-1R,2R-diaminocyclohexane)trans-(acetate)2(9-ethylguanine)Cl]NO3 · H2O P21 a = 10.446 b = 22.906 c = 10.978 Z = 4 [65]
Chloro-(homopiperazine)-(diphenylsulfido)-platinum(ii) nitrate [PtII(homopiperazine)(diphenylsulfide)Cl]NO3 monoclinic P21/c a 17.666 b 8.812 c 12.619 β 101.02° [66]
mmap=1-methyl-4-(methylamino)piperidine [Pt(mmap)(CH3)2S)Cl](NO3) white [67]
dhq=decahydroquinoline [Pt(dhq)(CH3)2S)Cl](NO3) [67]
[La(NO3)2(H2O)6]2[PtCl6]·2H2O monoclinic P21/c a = 6.974 b = 16.545 c = 13.177 β = 93.97° Z=2 yellow [68]
[Pr(NO3)2(H2O)6]2[PtCl6]·2H2O monoclinic P21/c a = 6.955 b = 16.525, c = 13.18.5 β = 93.93° Z=2 yellow [68]
[Gd(NO3)(H2O)7][PtCl6]·4H2O monoclinic P21/n a = 8.3872 b = 21.3198 c = 11.4263 β = 95.670° Z=4 yellow [68]
[Dy(NO3)(H2O)7][PtCl6]·4H2O monoclinic P21/n a = 8.3840 b = 21.3950 c = 11.4310 β = 95.698° Z=4 yellow [68]
Ir[NO3]2Cl[NH3]5 tetragonal I4 a = 7.6061 c = 10.4039 601.89 2.410 yellow [42]
{Cp*2Ir2[Ni(pyterpy)2]Cl4}(NO3)2 [45]
Dichloro(ethylenediamine)gold(III) nitrate [Au(NH2CH2CH2NH2)Cl2]NO3 orthorhombic Pbca a = 10.338 b = 8.2105 c = 19.625 Z=8 [69]
(2,2'-Bipyridine)dichlorogold(III) nitrate [AuCl2(C10H8N2)]NO3 486.06 monoclinic C2/c a 6.9240 b 14.0460 c 13.0560 β 96.562° Z=4 1261.44 2.559 pale yellow [70]
Bis(methy1 L-cysteineato)mercury(II) hydrochloride hydronitrate monohydrate (C4H9NO2S)2ClHgNO3•H2O [71]
chloronitrato-2-{2′-[(1′-methyl)benzimidazolyl]}- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxidemercury(II) – mercury(II)chloride HgCl(NO3)(C15H19N4O2) · HgCl2 triclinic P1 a=9.922 b=10.822 c=11.460 α=107.518° β=102.046° γ=96.639° Z=2 1126.5 black [72]
caesium mercuric nitrate chloride CsHgNO3Cl2 1:2 466.41 hexagonal P63/mmc a=5.8817 c=11.3920 Z=2 341.30 4.538 birefringent Δn = 0.145@546 nm [73]
4-chloropyridinium (C5H5NCl)2[UO2Cl3(NO3)] 1:3 triclinic P1 a=6.819 b=10.781 c=14.252 α=72.890° β=80.394° γ=74.456° Z=2 960.3 2.308 [74]
4-bromopyridinium (C5H5NBr)2[UO2Cl3(NO3)] 1:3 756.41 monoclinic P21/m a =9.739 b =16.484 c =12.950 β =102.360° Z=4 2030.8 2.474 [74]
4-iodopyridinium (C5H5NI)3[UO2Cl3(NO3)](NO3) 2:3 559.20*2 monoclinic P21/c a =7.9797 b =25.043 c =14.730 β =103.019° Z=4 2868.0 2.590 [74]
pyr2phen = N,N′-bis-(pyridoxylideneiminato)2−phenylene

(N-(3-Hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-ylmethylidene)-N'-(5-(hydroxymethyl)-2-methyl-3-oxypyridin-4-ylmethylidene)-o-phenylenediamine-N,N',O,O')-chloro-dioxo-uranium nitrate dihydrate

[UO2(H2pyr2phen)Cl]NO3 triclinic P1 a 9.231 b 11.855 c 14.026 α 114.8° β 94.012° γ 97.95° [75]
K3[(UO2)(NO3)Cl3](NO3) monoclinic P21 a 7.8596 b 15.8675 c 10.6823 β 90.141° Z=4 1332.21 3.08 [76]
Cs2(UO2)(NO3)Cl3 1:3 704.21 monoclinic P21/n a=10.375 b=9.468 c=12.553 β= 110.280 Z=4 1156.7 4.04 lemon yellow [77]
bis(4-iodo-pyridinium) dinitrato-tetrachloro-plutonium(iv) (C5H5NI)2[Pu(IV)Cl4(NO3)2] triclinic P1 a =9.8096 b=10.1402 c=11.5033 73.416  82.364 87.100 Z=2 1086.8 2.811 orange [78]
bis(pyridinium) trinitrato-trichloro-plutonium(iv) (C5H6N)2[Pu(IV)Cl3(NO3)3] 694.60 monoclinic P21/c a 17.268 b 7.7622 c 15.112 β 97.598° Z=4 2007.8 2.298 dark red [78]
bis(4-chloro-pyridinium) dioxo-trichloro-nitrato-plutonium(vi) (C5H5NCl)2[Pu(VI)O2Cl3(NO3)] 671.46 triclinic P1 a 6.7493 b 10.8107 c 14.171 α 73.657° β 81.412° γ 75.206° Z=2 956.0 2.333 yellow [78]

References

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