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Louis Frederick was a general in the cavalry. He was briefly a high ranking commander the Army of the Polish-Lithuanian Commonwealth appointed the commander of the Grand Duchy of Lithuania's army, but betrayed the Commonwealth, refusing to fight against Russian troops throughout the Polish–Russian War of 1792, while feigning illness. For his betrayal he was dismissed from his post, but never prosecuted.[1] His Polish wife, Duchess Maria, divorced him shortly afterward after his treason became public knowledge.
Between 1807 and 1810, Duke Louis employed the composer Carl Maria von Weber as his secretary with no musical duties. Weber and the duke's older brother Frederick mutually disliked each other, and the composer was banished from Württemberg after accusations of misappropriating some of the duke's money.