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Americium dioxide

Americium dioxide
Americium dioxide
Names
IUPAC name
Americium(IV) oxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.324 Edit this at Wikidata
EC Number
  • 234-471-0
  • InChI=1S/Am.2O/q+4;2*-2 ☒N
    Key: GABXYUQCUHMHDP-UHFFFAOYSA-N ☒N
  • [O--].[O--].[Am+4]
Properties
AmO2
Molar mass 275 g·mol−1
Appearance Black crystals
Density 11.68 g/cm3
Melting point 2,113 °C (3,835 °F; 2,386 K)[1]
Structure[1]
Fluorite (cubic), cF12
Fm3m, No. 225
a = 537.6 pm
4
Related compounds
Other cations
 Plutonium(IV) oxide
Curium(IV) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Americium dioxide (AmO2) is a black[2] compound of americium. In the solid state, AmO2 adopts a fluorite structure (like CaF2).[3] It is used as a source of alpha particles.

Historical context

The demand for americium dioxide stems from the difficulty of storing the element americium as a solution of americium(III) chloride because the alpha radiation and hydrochloric acid decomposes storage containers over time. To solve the liquid storage problem, scientists at Oak Ridge National Laboratory devised a synthesis to turn liquid americium–acid solution into a precipitated form of americium for safer handling and more efficient storage.[4]

Synthesis

Synthesis of americium dioxide, as described by the Oak Ridge National Laboratory in 1960, starts by dissolving americium in hydrochloric acid, and then neutralizing the excess acid with ammonium hydroxide (NH
4OH). Then, saturated oxalic acid solution (C
2H
2O
4) is added to the now neutralized solution to precipitate dull pink americium(III) oxalate crystals; once complete precipitation is achieved, additional oxalic acid is added to make a slurry. The slurry of americium oxalate and oxalic acid is next agitated before the americium oxalate is filtered out, washed with water, and partially dried in air.[4]

The americium oxalate is then calcinated in a platinum boat. It is first dried in a furnace at 150 °C (302 °F) and then heated to 350 °C (662 °F). When decomposition begins to occur, the oxalate will turn into the desired black americium dioxide; to ensure no oxalate remains in the newly forming dioxide, the oven temperature is increased and held at 800 °C (1,470 °F) then slowly allowed to cool to room temperature.[4]

Modern applications

Americium dioxide is the most widely used americium compound in ionising smoke detectors. The dioxide form is insoluble in water, making it relatively safe to handle in production.

In the late 2010s, americium dioxide has been of interest to ESA as power source for radioisotope thermoelectric generators (RTGs) for deep space exploration spacecraft and satellites. A fully automated chemical process to produce americium dioxide was developed by nuclear researchers from the University of Bristol to be implemented on the Sellafield nuclear site in Cumbria, UK. It is based on the same principles as the historic production method developed at Oak Ridge National Laboratory.[5]

Americium-aluminium alloys

Americium-aluminium alloys can be formed by melting americium dioxide with aluminium and an additional fluxing agent.[6] The created alloy can undergo neutron irradiation to produce other transuranic nuclides.[7]

References

  1. ^ a b Christine Guéneau; Alain Chartier; Paul Fossati; Laurent Van Brutzel; Philippe Martin (2020). "Thermodynamic and Thermophysical Properties of the Actinide Oxides". Comprehensive Nuclear Materials 2nd Ed. 7: 111–154. doi:10.1016/B978-0-12-803581-8.11786-2. ISBN 9780081028667. S2CID 261051636.
  2. ^ Greenwood, Norman N. & Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Pergamon Press. p. 1267. ISBN 978-0750633659. LCCN 97036336. OCLC 1005231772. OL 689297M.
  3. ^ Wells, Alexander Frank (1984). Structural inorganic chemistry. Oxford: Clarendon Press. ISBN 978-0-19-855370-0.
  4. ^ a b c "Preparation of Americium Dioxide by Thermal Decomposition of Americium Oxalate in Air" (PDF). Oak Ridge National Laboratory. December 1960. Retrieved 2 May 2013.[permanent dead link‍]
  5. ^ Verbelen, Yannick; Megson-Smith, David; Holland, Erin (2020). "Am2RTG: Am2RTG: Fully Autonomous, Rad-Hard Americium Nitrate to Americium Dioxide Conversion Process Flow for Radioisotope Thermoelectric Generators". doi:10.13140/RG.2.2.28490.80320. {{cite journal}}: Cite journal requires |journal= (help)
  6. ^ "Preparation of Americium-Aluminium Alloys". KERNFORSCHUNG GMBH GES FUER. January 1974. Archived from the original on 2013-06-29. Retrieved May 3, 2013.
  7. ^ "Toxicological profile for americium" (PDF). U.S. Department of Health and Human Services. April 2004. Retrieved 15 January 2011.
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